Now a days TV Show Gossip Girl now become most pouplar to making matched It's no surprise when actors fall in love while working closely together on set. Look at Bogie and Bacall, Tom Hanks and Rita Wilson and Bennifer (Part 2). Of course, there are those far more scandalous instances when a spouse is involved (i.e. Meg Ryan and Russell Crowe, Ryan Phillippe and Abbie Cornish and the poster couple for did-they-or-didn't-they, Brangelina).

Gossip Girl is the one of the most popular TV show now, as Hollywood history proves, it's safe to assume the same would happen to a cast of young, ridiculously good-looking people like those from Gossip Girl. The long hours, close quarters and buttoned-up cashmere cardigans would make anyone go crazy, right? But in this case, Cupid has been working overtime to turn GG's romances from reel to real life. Let's take a look at the misses and matches:

Penn Badgley and Blake Lively: Penn and Blake have known each other since they were 11-years-old, but the sparks didn’t fly until they began working on Gossip Girl in 2007. They’ve remain one of the most solid couples in Young Hollywood and often keep a low profile. Lucky for them, their on-screen character’s off-and-on romance has been a continuing storyline for Gossip Girl. While their GG relationship is back off, their Leighton Meester Sebastian Stan Gossip Girlon-screen love remains strong. A source close to the starlet said the inseparable lovers are engaged - and they made the announcement on their “secret” Facebook pages. “Gossip Girl” star Meester and Stan have been dating since they met on the set of the show last year, when Sand played a character who was featured in two early episodes.

Leighton Meester and Sebastian Stan: Both couples were spotted canoodling at the Armani Exchange dinner for Nylon magazine’s Young Hollywood issue. While some believe Leighton fell for Sebastian after his first season guest appearance on Gossip Girl, it was actually co-star Chace Crawford who played Cupid for the couple. Together since last year, Leighton and Sebastian took their love on-screen in this past week’s episode where Sebastian’s bad boy character Carter Baizen tempts Blaire over to the dark side. Leighton gushes, "He reminds me of Ray Liotta."Chace Crawford Taylor Momsen Gossip Girl. Gossip Girl cutie Leighton Meester (in YSL) shares a sweet moment with actor boyfriend Sebastian Stan at the Season 2 premiere of Gossip Girl. Sebastian, who turned 25 earlier this month, had two small appearances on Gossip Girl as wealthy bad boy Carter Baizen (pictured below). It would seem that hooking up on the Gossip set is the way to do things these days!

Chace Crawford and Taylor Momsen: The photo to the left is the second saucy shot of J herself, Jenny (Taylor Momsen), canoodling with Nate (Chace Crawford), which has many of you fans asking: What is the deal? Are they really getting together? How long will it last? If you really want to know, keep reading... According to inside sources, the real story with Jenny and Nate is that they will "kiss a couple of times" and then...She gets pregnant. Either that, or the whole thing ends abruptly and they never become a real couple. While their romance didn't last long, Chace and Taylor were another couple who's relationship went from reel to real. Despite their eight year age difference, rumors spread like wild fire when gossip sites caught Chace and Taylor smooching at a number of places in New York City. But that was short-lived. Whether or not the rumors were true, Chace and Taylor remain to be two of the last single people on the GG cast. That's good news for the ladies!

Jessica Szohr and Ed Westwick : Ed Westwick (so much for those gay rumors) and Jessica Szohr were snapped smooching last night in NYC. The cute costars were reportedly nuzzling and whispering throughout the game of hoops between the Knicks and the Lakers. Ed looks really into it, doesn't he? But what's Jess thinking about? The latest Gossip Girl romance to stun fans (and disappoint women) is that of Jessica and Ed. The two were first outed as a couple when Jessica and Ed were seen spending Thanksgiving weekend together. They have since become attached at the hip, whether it's at a Knicks game or trips to Miami. While they appear to be frenemies on-screen, GG fans will get quite the OMG moment when Jessica and Ed join forces to stir up some revenge on next week's episode.